Ruthenium redox equilibria: 2. Thermodynamic analysis of disproportionation and comproportionation conditions
نویسندگان
چکیده
منابع مشابه
Ruthenium redox equilibria: 2. Thermodynamic analysis of disproportionation and comproportionation conditions
The key property of Frost diagram has been confirmed using thermodynamic and linear algebra methods. On the basis of the thermodynamic data, the areas of thermodynamic stability of ruthenium species of different valence states as a function of pH for each degree of oxidation have been determined. Subsequently, based on the diagrams calculated for several values of pH, a narrow ΔpH value is dete...
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ژورنال
عنوان ژورنال: Journal of Electrochemical Science and Engineering
سال: 2016
ISSN: 1847-9286
DOI: 10.5599/jese.228